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61.
62.
Shi Z Liu J Lin T Xia F Liu PN Lin N 《Journal of the American Chemical Society》2011,133(16):6150-6153
We investigated the thermodynamic processes of two-dimensional (2D) metallo-supramolecular self-assembly at molecular resolution using scanning tunneling microscopy and variable-temperature low-energy electron diffraction. On a Au(111) substrate, tripyridyl ligands coordinated with Cu in a twofold Cu-pyridyl binding mode or with Fe in a threefold Fe-pyridyl binding mode, forming a 2D open network structure in each case. The network structures exhibited remarkable thermal stability (600 K for the Cu-coordinated network and 680 K for the Fe-coordinated network). The Fe-pyridyl binding was selected thermodynamically as well as kinetically in self-assembly involving both modes. The selectivity can be effectively suppressed in a specifically designed self-assembly route. 相似文献
63.
Simultaneous Determination of Cimaterol, Salbutamol, Terbutaline and Ractopamine in Feed by SPE Coupled to UPLC 总被引:2,自引:0,他引:2
Chun Hua Qu Xian Liang Li Lei Zhang Cun Xian Xi Guo Ming Wang Nian Bing Li Hong Qun Luo 《Chromatographia》2011,73(3-4):243-249
An ultra performance liquid chromatography (UPLC) method was established for the simultaneous determination of cimaterol, salbutamol, terbutaline, and ractopamine in feed. Target compounds were extracted with methanol and centrifuged. The supernatant was then transferred and concentrated, and applied to a solid phase extraction MCX cartridge for clean-up before UPLC analysis. The calibration curves for the four ??-agonists were good linear in concentration range of 0.05?C1.0 ??g mL?1 with the correlation coefficients (r) over 0.999. The average recoveries were in the range of 90.1?C101.4% with relative standard deviation values lower than 8.0%. 相似文献
64.
Wang W Wang S Hong Y Tang BZ Lin N 《Chemical communications (Cambridge, England)》2011,47(36):10073-10075
We studied the supramolecular assembly of a multifunctional ligand, cis-bis-terpyridine tetraphenyl ethylene, on a Cu(111) surface by low-temperature scanning tunneling microscopy (STM). Three distinctive supramolecular structures, metallacycles, propeller-shaped clusters and extended linear chains, are formed under specific assembly conditions owing to different inter-molecular binding modes of Cu-coordination, van der Waals interaction and hydrogen bonding, respectively. 相似文献
65.
Huang WT Shi Y Xie WY Luo HQ Li NB 《Chemical communications (Cambridge, England)》2011,47(27):7800-7802
Herein, we demonstrate the first use of a reduced graphene oxide (rGO)-organic dye nanoswitch for the label-free, sensitive and selective detection of Hg(2+) using bifunctional rGO as an effective nanoquencher and highly selective nanosorbent. Moreover, a reversible on-off INHIBIT rGO logic gate based on a cysteine-Hg(2+) system has also been designed. 相似文献
66.
In a recent paper, Nguyen et al. (2018) built a distributionally robust estimator for the precision matrix of the Gaussian distribution. The distributional uncertainty size is a key ingredient in the construction of this estimator. We develop a statistical theory which shows how to optimally choose the uncertainty size to minimize the associated Stein loss. Surprisingly, rather than the expected canonical square-root scaling rate, the optimal uncertainty size scales linearly with the sample size. 相似文献
67.
讨论了对二维核磁共振数据进行噪声剔除与数据压缩的一般原理与方法,介绍在Sun图形工作站上的实现情况,并给出实验结果与分析。 相似文献
68.
ChunHuiZHOU ZhongHuaGE XiaoNianLI HongQiangGUO JianSUN 《中国化学快报》2003,14(12):1285-1288
A mesoporous titanium/silicon -containing montmorillonite-based catalytic materials has been synthesized by novel gallery-templated techniques. XRD, SEM, framework IR, and N2 adsorption-desorption isotherms provided evidence of the formation of Si/Ti pillars. The synthetic materials show potential catalytic application for hydroxylation of phenol with peroxide. 相似文献
69.
Wei Nian Li 《Journal of Mathematical Analysis and Applications》2006,319(2):802-814
In this paper, based on some known dynamic inequalities, we investigate certain new dynamic inequalities on time scales, which provide explicit bounds on unknown functions. Our results unify and extend some continuous inequalities and their corresponding discrete analogues. 相似文献
70.
lnthepreviouspaper',wereportedtheintramolecularcyclizationsofamide4anditscis-eneisomerinanattempttosynthesizehomoclausenamideandzetaclausenamide2.Inordertostudytherelationshipbetweenthestereochemistryandtheilltramolecularcyclizationofthisseriesofcompounds,theamides5(cis-oxirane,trans-ene)and8(cis-oxirane,cis-ene)wereprepared,andtheirintramolecularcyclizationswerereportedinthispaper.Theamide5withm.p.152.O-l54.O"CwasobtainedfromDarzen'scondensationofcompound3withPhCHOinMeOHatl5-2OoCwithMeO… 相似文献